Danylo Sikan's header led Shakhtar Donetsk to a 1-0 victory over Barcelona in the Champions League Group H match.
Barcelona needed one point to secure a spot in the last 16 but fell short in this game.
Barcelona managed only one shot on target during the match.
Sikan's goal in the 40th minute gave Shakhtar the lead.
Giorgi Gocholeishvili set up Sikan's header for the goal.
The Ukrainian side was aggressive on the counter-attack.
Shakhtar goalkeeper Dmytro Riznyk made crucial saves to keep Barcelona at bay.